On-line purge and trap GC-MS for monitoring 1,3-dichloropropene in agricultural water and soil samples.

نویسندگان

  • Antonia Garrido Frenich
  • Salvador Cortés Aguado
  • José Luis Martínez Vidal
  • Francisco Javier Arrebola
چکیده

A simple and reliable method using on-line purge and trap gas chromatography mass spectrometry has been developed for the determination of the fumigant 1,3-dichloropropene (1,3-DCP) in agricultural water and soil samples. The proposed analytical methodology was validated in the target environmental matrices by the analysis of spiked blank matrix samples. Limit of detection values of 0.05 microg/L for water and 0.005 microg/Kg for soils were obtained, while limits of quantitation were of 0.1 microg/L for water and 0.01 mg/kg for soils. Good recoveries (93-104%) and precision values (< 6%) were obtained for the target compound in the studied matrices. This methodology has been successfully applied to the analysis of incurred groundwater samples from an agricultural area, The Campo de Dalías (Almería, South Spain), although 1,3-DCP was not detected. The method was also applied to soil samples from greenhouse treated with a soil fumigant containing 1,3-DCP.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Trace-level determination of 1,4-dioxane in water by isotopic dilution GC and GC-MS.

The volatile and polar solvent 1,4-dioxane has recently been reported as a contaminant of ground and surface waters, establishing the need to determine this substance in drinking water. This investigation established that 1,4-dioxane can be determined in water by various techniques including direct aqueous injection (DAI) gas chromatography (GC) and purge and trap GC-mass spectrometry (MS). Pur...

متن کامل

Analysis of High Concentrations of MTBE and BTEX in Soil and Solid Waste Samples

The FROG-4000TM Portable GC System Weighing less than 5 pounds, the FROG4000TM (shown in Figure 1) is the smallest portable GC system on the market today. The FROGTM uses MEMS components and designer nanomaterials to deliver the same detection capabilities of a traditional bench top GC system but at a fraction of the cost and size. The FROG-4000TM is equipped with a purge-and-trap system for an...

متن کامل

Analysis of High Concentrations of MTBE and BTEX in Soil and Solid Waste Samples

D company The FROG-4000TM Portable GC System Weighing less than 5 pounds, the FROG4000TM (shown in Figure 1) is the smallest portable GC system on the market today. The FROGTM uses MEMS components and designer nanomaterials to deliver the same detection capabilities of a traditional bench top GC system but at a fraction of the cost and size. The FROG-4000TM is equipped with a purge-and-trap sys...

متن کامل

Techniques for Optimizing the Analysis of Volatile Organic Compounds in Water Using Purge-and-Trap/GC/MS Application

The analysis of volatile organic compounds in water is normally accomplished by purge-and-trap/gas chromatography/mass spectrometry. U.S. EPA Method 8260B with purge and trap sample introduction is widely used for the analysis of aqueous samples other than drinking water. This application note discusses problems that can arise and some easy solutions for them. These techniques have resulted in ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of chromatographic science

دوره 47 1  شماره 

صفحات  -

تاریخ انتشار 2009